HERO BX receives $1.6 million grant
to complete biodiesel expansion project
November 5, 2009 (Erie, PA) – HERO BX, the country's largest producer of biodiesel, has been awarded a $1,640,250 million grant from the Commonwealth Financing Authority.
HERO BX is matching the award amount with its own funds for a total of $3,280,500. The money will be used to complete the company's expansion project – increasing their yearly output of low-cost, high quality biodiesel, from 45 million gallons to 55 million gallons.
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“It is imperative that biofuels companies that are producing fuel today continue to receive financial support,” said Leonard Kosar, CEO of HERO BX. “The state of Pennsylvania is setting a precedent apart from the federal government and many other states – it has recognized the economic, environmental and security value of supporting biofuels companies that are already in production. We cannot and will not be able to produce the next generation of biodiesel and ethanol if we abandon first generation biofuels producers such as HERO BX.”
The grant was awarded as part of Governor Edward G. Rendell's goal to increase alternative energy opportunities within the state. The funds, which will be distributed through Green Energy Works!, is part of the federal funding that the state will receive under the American Reinvestment and Recovery Act (Stimulus Bill).
The program goal is to invest more than $99.6 million of federal funding to supplement the state's Alternative Energy Investment Fund. There is a huge economic opportunity for Pennsylvania to produce biofuels.
Through its “Sustainable Crops Initiative,” HERO BX is working with agronomists at Pennsylvania State University to pioneer the use of the camelina. The crop is an ideal feedstock because it's a weed that grows in sub-optimum soil, doesn't need water or fertilizer and produces seven times more oil than soybeans.
In addition, the high Omega-3 by-product has been approved for use in poultry feed. In Pennsylvania alone, there are 200,000 acres of old strip mines that are ideal for growing the feedstock.
“We anticipate that we'll be producing 20-25 percent of our biodiesel using the second-generation feedstock, camelina within the next 2-3 years,” said Kosar. “Unlike many other companies that are simply developing technology using second and third generation feedstocks to produce biofuels someday, we are profitably producing biofuels today.”
About HERO BX HERO BX, formerly Lake Erie Biofuels, LLC, started operations in 2007 and is Pennsylvania's first large-scale biodiesel production facility. A fully accredited BQ-9000 producer and marketer of biodiesel, HERO BX is the leading producer of biodiesel in the United States and distributes its fuel around the world. |
Two-step chemical process
turns raw biomass into biofuel
by Nicole Miller
MADISON, WI –– Taking a chemical approach, researchers at the University of Wisconsin-Madison have developed a two-step method to convert the cellulose in raw biomass into a promising biofuel.
The process, which is described in the Wednesday, Feb. 11 issue of the Journal of the American Chemical Society, is unprecedented in its use of untreated, inedible biomass as the starting material.
The key to the new process is the first step, in which cellulose is converted into the "platform" chemical 5-hydroxymethylfurfural (HMF), from which a variety of valuable commodity chemicals can be made.
"Other groups have demonstrated some of the individual steps involved in converting biomass to HMF, starting with glucose or fructose," says Ronald Raines, a professor with appointments in the Department of Biochemistry and the Department of Chemistry. "What we did was show how to do the whole process in one step, starting with biomass itself."
Raines and graduate student Joseph Binder, a doctoral candidate in the chemistry department, developed a unique solvent system that makes this conversion possible.
The special mix of solvents and additives, for which a patent is pending, has an extraordinary capacity to dissolve cellulose, the long chains of energy-rich sugar molecules found in plant material. Because cellulose is one of the most abundant organic substances on the planet, it is widely seen as a promising alternative to fossil fuels.
"This solvent system can dissolve cotton balls, which are pure cellulose," says Raines. "And it's a simple system-not corrosive, dangerous, expensive or stinky."
This approach simultaneously bypasses another vexing problem: lignin, the glue that holds plant cell walls together. Often described as intractable, lignin molecules act like a cage protecting the cellulose they surround.
However, Raines and Binder used chemicals small enough to slip between the lignin molecules, where they work to dissolve the cellulose, cleave it into its component pieces and then convert those pieces into HMF.
In step two, Raines and Binder subsequently converted HMF into the promising biofuel 2,5-dimethylfuran (DMF). Taken together, the overall yield for this two-step biomass-to-biofuel process was 9 percent, meaning that 9 percent of the cellulose in their corn stover samples was ultimately converted into biofuel.
"The yield of DMF isn't fabulous yet, but that second step hasn't been optimized," says Raines, who is excited about DMF's prospects as a biofuel. DMF, he notes, has the same energy content as gasoline, doesn't mix with water and is compatible with the existing liquid transportation fuel infrastructure. It has already been used as a gasoline additive.
In addition to corn stover, Raines and Binder have tested their method using pine sawdust, and they're looking for more samples to try out. "Our process is so general I think we can make DMF or HMF out of any type of biomass," he says.
Raines's first foray into biofuels development was supported by the Great Lakes Bioenergy Research Center, a U.S. Department of Energy bioenergy research center located at the UW-Madison. Additional support was provided through a National Science Foundation Graduate Research Fellowship awarded to Binder.
Note: For a brief bio of Ronald T. Raines, click here . . .
Iowa State Univ. researcher identifies protein
that concentrates carbon dioxide in algae
AMES, IA –– Increasing levels of carbon dioxide in the atmosphere are a concern to many environmentalists who research global warming. The lack of atmospheric carbon dioxide (CO2) concentration, however, actually limits the growth of plants and their aquatic relatives, microalgae.
For plants and microalgae, CO2 is vital to growth. It fuels their photosynthesis process that, along with sunlight, manufactures sugars required for growth.
CO2 is present in such a limiting concentration that microalgae and some plants have evolved mechanisms to capture and concentrate CO2 in their cells to improve photosynthetic efficiency and increase growth.
An Iowa State University researcher has now identified one of the key proteins in the microalgae responsible for concentrating and moving that CO2 into cells.
"This is a real breakthrough," said Martin Spalding, professor and chair of the department of genetics, development and cell biology. "No one had previously identified any of the proteins that are involved in transporting CO2 in microalgae."
The main protein that Spalding and his team have identified that is responsible for transporting CO2 is called HLA3.
The research by Spalding; Deqiang Duanmu, a graduate student in Spalding's department; and Amy Miller, Kempton Horken and Donald Weeks, all from the University of Nebraska, Lincoln; is published in the current issue of the journal Proceedings of the National Academy of Sciences of the United States of America.
Now that the HLA3 protein has been identified, Spalding believes there are several possibilities to use the gene that encodes this protein.
The recent explosion of interest in using microalgae for production of biofuels raises the possibility of increasing photosynthesis and productivity in microalgae by increasing expression of HLA3 or other components of the CO2 concentrating mechanism, according to Spalding.
Since all plants need CO2 to thrive, introducing the HLA3 gene into plants that do not have the ability to concentrate CO2, could help those plants grow more rapidly. Spalding says several plants would be candidates for the HLA3 protein.
"One of the things we've been working on is the prospect that we may be able to take components of the CO2 concentrating mechanism for microalgae, such as this HLA3, and put it into something like rice and improve photosynthesis for rice," said Spalding.
Rice and other commodity crops such as wheat and soybeans do not have any CO2 concentrating mechanism.
New biofuels process promises
to meet all U.S. transportation needs
WEST LAFAYETTE, IN –– Purdue University chemical engineers have proposed a new environmentally friendly process for producing liquid fuels from plant matter - or biomass - potentially available from agricultural and forest waste, providing all of the fuel needed for "the entire U.S. transportation sector."
The new approach modifies conventional methods for producing liquid fuels from biomass by adding hydrogen from a "carbon-free" energy source, such as solar or nuclear power, during a step called gasification.
Adding hydrogen during this step suppresses the formation of carbon dioxide and increases the efficiency of the process, making it possible to produce three times the volume of biofuels from the same quantity of biomass, said Rakesh Agrawal, Purdue's Winthrop E. Stone Distinguished Professor of Chemical Engineering.
The researchers are calling their approach a "hybrid hydrogen-carbon process," or H2CAR.
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Rakesh Agrawal, Purdue's Winthrop E. Stone Distinguished Professor of Chemical Engineering. |
| Photo: Purdue Univ, |
"Further research is needed to make this a large-scale reality," Agrawal said. "We could use H2CAR to provide a sustainable fuel supply to meet the needs of the entire U.S. transportation sector - all cars, trucks, trains and airplanes."
The process, which would make possible the dawning of a "hydrogen-carbon economy," is detailed in a research paper appearing online this week in the Proceedings of the National Academy of Sciences. The paper was written by Agrawal, chemical engineering doctoral student Navneet R. Singh, and chemical engineering professors Fabio H. Ribeiro and W. Nicholas Delgass.
A conventional method for turning biomass or coal into liquid fuels involves first breaking down the raw material with a chemical process that "gasifies" it into carbon dioxide, carbon monoxide and hydrogen. Then those constituents are turned into a liquid fuel with other processes.
In the H2CAR concept, hydrogen would be harvested by splitting water molecules, possibly with a well-known method called electrolysis. Then the hydrogen would be added during the gasification step, making the process more efficient by suppressing the formation of carbon dioxide and converting all of the carbon atoms to fuel.
When conventional methods are used to convert biomass or coal to liquid fuels, 60 percent to 70 percent of the carbon atoms in the starting materials are lost in the process as carbon dioxide, a greenhouse gas, whereas no carbon atoms would be lost using H2CAR, Agrawal said.
"This waste is due to the fact that you are using energy contained in the biomass to drive the entire process," he said. "I'm saying, treat biomass predominantly as a supplier of carbon atoms, not as an energy source."
Power for the electrolysis would be provided by carbon-free energy sources, such as solar, wind or nuclear power. And, unlike conventional methods of producing liquid fuels from plant matter and coal, H2CAR would not emit carbon dioxide into the atmosphere.
"The goal is to accomplish the complete transformation of every carbon atom in the feedstock to liquid fuel by supplementing the conversion process with hydrogen from a carbon-free energy source," Agrawal said.
Other researchers have estimated that the United States has a sustainable supply of about 1.4 billion tons of biomass each year that could be used specifically for the production of liquid fuels. With conventional methods, that quantity of biomass would provide 30 percent of the fuel required for the nation's annual transportation needs. But the same quantity of biomass would provide enough fuel to meet all transportation needs using the new H2CAR method, Agrawal said.
"This is possible without using any additional land," he said.
A federal study indicates that 1 billion tons of biomass is potentially available every year from agricultural sources such as crop wastes, animal manure, grains and other crops. The remaining biomass could come from sources including fuel wood from forests, wastes left over from wood processing mills and paper mills, and construction and demolition debris.
The process also offers potential advantages over producing liquid fuels from coal using conventional methods, which emit carbon dioxide. Because H2CAR would not emit this additional carbon dioxide, the process would eliminate the need for proposed carbon dioxide "sequestering."
Sequestering would involve pumping carbon dioxide emissions into saltwater aquifers and hollow underground pockets that used to contain oil, natural gas and coal deposits. But the procedure poses several potential pitfalls.
"Clearly, massive quantities of carbon dioxide would be sequestered during a century-long production of liquid fuels from coal," Agrawal aid. "This would place extreme demands on the carbon dioxide capture, storage and monitoring systems."
The new process also would be more practical than all-electric or hydrogen-powered cars, in part because of the limited storage capacity of batteries and hydrogen storage tanks.
"The tremendous convenience provided by the existing infrastructure for delivering and storing today's fuels is a huge deterrent to introducing technologies that use only batteries or hydrogen alone," Agrawal said. "A major advantage of our process is that it would enable us to use the current infrastructure and internal combustion engine technology. It is quite attractive for hybrid electric vehicles and plug-in hybrid electric vehicles."
To grow enough biomass for the entire nation's transportation needs using the conventional method for producing biofuels would require a land area 25 percent to 55 percent the size of the United States, compared with about 6 percent to 10 percent for the H2CAR process.
"This large reduction of land area needed for H2CAR provides an opportunity for sustainable production of hydrocarbon fuel for the foreseeable future," Agrawal said.
A major reason less land would be needed is because of the overall higher efficiency of generating hydrogen by splitting water molecules using solar energy to drive the electrolysis.
Usually, the hydrogen in liquid fuels made from biomass comes from the plant matter itself. But it typically takes more than 10 times the solar energy to grow crops than it does to produce the equivalent quantity of hydrogen possessing the same energy content by using the solar-power electrolysis method, he said.
"So providing hydrogen derived from water through solar electrolysis reduces the amount of biomass needed," Agrawal said. "The average energy efficiency of growing crops is typically less than 1 percent, whereas the energy efficiency of photovoltaic cells to split water into hydrogen and oxygen is about 8-10 percent. I am getting hydrogen at a higher efficiency than I get biomass, meaning I need less land."
Using coal exclusively to produce liquid fuels for the nation's transportation sector could deplete all coal deposits in the United States in about 90 years, whereas H2CAR would enable the known coal reserves to last 140 years.
The researchers suggest in the paper the chemical processing steps needed to make the new approach practical. But making the concept economically competitive with gasoline and diesel fuel would require research in two areas: finding ways to produce cheap hydrogen from carbon-free sources and developing a new type of gasifier needed for the process.
"Having said that, this is the first concept for creating a sustainable system that derives all of our transportation fuels from biomass," Agrawal said.
Purdue has filed a patent for the concept. The approach is in the conceptual stages, and a plan for experimental research is in progress.
The work is supported by the Energy Center in Purdue's Discovery Park.
Like to the the report: Sustainable Fuel for the Transporation Sector
Innovative Glycerol Combustion System
Demonstrated by Diversified Energy®
Files Patent, and Seeks Commercialization Partners
GILBERT, AZ –– Diversified Energy® Corporation announced the successful demonstration of a combustion system that offers the global bio-diesel industry an economically attractive use for their crude glycerol.
Under an exclusive worldwide license to Diversified Energy, the breakthrough system developed by North Carolina State University can safely and efficiently burn the glycerol byproduct generated during the manufacture of bio-diesel.
The energy created through the combustion of glycerol can then be used for process heating applications or electricity generation.
The university has built and tested a 100,000 Btu/hour prototype burner, U.S. and international patents have been filed, and Diversified Energy is seeking commercialization partners for market introduction.
The manufacture of bio-diesel through transesterification results in approximately one pound of crude glycerol byproduct for every nine pounds of bio-diesel produced.
Due to the rapid growth in the bio-diesel industry, crude glycerol supplies have also increased. Supplies are expected to grow to well more than 350,000 tons per year in the U.S. and 600,000 tons per year in Europe.
Crude glycerol contains artifacts from the bio-diesel process like catalysts, alcohol, and soap and is therefore costly to refine into higher grade, pure glycerol.
Consequently, crude glycerol market prices have collapsed and the bio-diesel industry is struggling with viable options for the glut of glycerol on hand.
The combustion of crude glycerol offers an elegant solution, where 16 MJ (megajoules) of heat per kilogram of glycerol burned could be provided back to the bio-diesel process, another co-located system, or converted into other energy forms like electricity.
However, the combustion of glycerol has been challenging because of technical, safety, and cost obstacles.
By nature, glycerol has a high viscosity, high auto-ignition temperature, and low heating value. This means it is difficult to flow the product into a burner, hard to ignite, and even more challenging to maintain a flame. In addition, if the glycerol is not completely combusted, it is possible to generate toxic gases.
For this reason the market has struggled to commercialize cost-effective, widely deployable combustion systems for crude glycerol.
The patent-pending process from NC State University is based on a novel spray atomization swirl burner architecture that overcomes all technical and safety issues.
This is coupled with a unique approach to pre-heat the combustion chamber, maintain heat retention, maximize radical retention, and carefully interact air and fuel flows.
The system is extendable to any liquid fuel having an ambient viscosity of greater than 20 centistokes.
A 100,000 Btu/hr prototype has been manufactured and tested with pure glycerol, crude glycerol from a bio-diesel process, and glycerol with water. Rigorous emissions characterization has been completed to showcase the system’s safety.
Diversified Energy is seeking partners to leverage the prototype into a commercial design, manufacture the system, and conduct market sales and service.
| About Diversified Energy Corporation Headquartered in Gilbert, Arizona (a suburb of Phoenix), Diversified Energy Corporation (www.diversified-energy.com) is a privately held alternative and renewable energy company focused on maturing innovative technologies, developing commercial energy projects, and providing engineering services support to project developers. Principal areas of expertise include bio-fuels, gasification, and algal biomass production. |
| About North Carolina State University: A nationally recognized leader in science and technology with historic strengths in agriculture and engineering, North Carolina State University provides a high-quality education in the humanities and social sciences, design, education, life sciences, management, natural resources, physical and mathematical sciences, textiles and veterinary medicine. Whether educating students for the 21st century, improving lives through life-altering research, or partnering with communities, business, and government to create jobs, NC State's commitment to innovation creates a culture of excellence that spreads to every facet of the university and affects people's lives in relevant, powerful ways. NC State’s Office of Technology Transfer manages the University’s patent and technology portfolio, currently consisting of 552 U.S. Patents and approximately 1600 proprietary technologies. Forming partnerships with innovative companies such as Diversified Energy fulfills NC State’s mission of getting academic discovery to the market for the greater public good. |
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